Curved glass constructions and methods for forming same

ABSTRACT

The disclosure relates to fame constructions comprising a glass substrate and a curved surface defining at least one curvature, wherein the engagement of the glass substrate with the curved surface imparts a curvature on the glass substrate.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims the benefit of priority under 35 U.S.C § 120 of U.S. Provisional Application Ser. No. 63/004,131 filed on Apr. 2, 2020 the content of which is relied upon and incorporated herein by reference in its entirety.

BACKGROUND

Methods for producing three-dimensional cold formed objects include adhering a glass component to a rigid frame using an adhesive interlayer to form a glass construction. In such methods, a significant portion of the glass component is mechanically stressed to form the shape, thereby placing shear or tensile stress on the adhesive interlayer for the lifetime of the glass construction, including while the interlayer cures. As soon as the glass component is mechanically stressed or formed, the interface between the glass component and the adhesive interlayer is under tension, shear or a combination of shear and tension. The presence of this tension and/or shear requires that the glass construction be clamped or mechanically restrained for a time sufficient for the adhesive interlayer to provide sufficient tack and substantial creep resistance, adding complexity to a manufacturing process. This time period can range from about five minutes to hours or more, depending on, among other things, the adhesive type and the application. In short, an adhesive that develops tack rapidly and cures quickly is generally required, which can add complexity to manufacturing. And the constant tension may eliminate use of adhesive (e.g., VHB) tapes due to creep. Further still, mechanical restraint of the glass from the edge for the life of the glass construction to keep it from delaminating is generally undesirable from an aesthetic standpoint. Another alternative is to use a combination of VHB tape for initial tack and liquid adhesive for long term adhesion. But such methods may not scalable to small frame widths, since VHB tape can only be made in strips of 2-3 mm, which would consume a significant portion of the bonding area. Addition of VHB tape also adds complexity in manufacturing.

SUMMARY

Accordingly, there is a need for methods for forming glass constructions that do not succumb to the aforementioned shortcomings of known methods. To that end, the disclosure provides, among other things, a frame construction comprising: a glass substrate having first and second major surfaces and at least one curvature; at least one connector layer including a plurality of mechanical restrains, the connector layer having third and fourth major surfaces; at least one adhesive layer located between the glass substrate second major surface and the connector layer third major surface; and a frame comprising a plurality of mechanical restrain receptacles engaging the plurality of mechanical restrains; wherein the frame comprises a curved surface comprising a radius of curvature of about 60 mm or greater; wherein the engagement of the plurality of mechanical restrain receptacles and the plurality of mechanical restrains at least initially maintains the at least one curvature of the glass substrate.

The disclosure also relates to a frame construction comprising: a glass substrate having first and second major surfaces and at least one curvature; a segmented frame having first and second opposing major surfaces and including at least one curved segment engaged with at least one substantially flat segment; and at least one adhesive layer located between at least a portion of the glass substrate second major surface and at least a portion of the segmented frame first major surface; wherein the at least one curved segment defines the at least one curvature, the at least one curvature having a bend radius of about 60 mm or greater; wherein the engagement of the at least one curved segment with the at least one substantially flat segment maintains the at least one curvature of the glass substrate.

DESCRIPTION OF THE DRAWINGS

The drawings illustrate generally, by way of example, but not by way of limitation, various embodiments discussed herein.

FIG. 1A is a side view of a glass construction according to the instant disclosure.

FIG. 1B is a side view of a glass construction according to the instant disclosure.

FIG. 10 is a side view of a glass construction according to the instant disclosure.

FIG. 1D is a side view of a glass construction according to the instant disclosure.

FIG. 1E is a perspective view of a glass construction according to the instant disclosure.

FIG. 1F is a bottom view of a patterned connector layer according to the instant disclosure.

FIG. 1G is a perspective view of the patterned connector layer shown in FIG. 1F according to the instant disclosure.

FIG. 2 is a side view of another glass construction according to the instant disclosure.

FIG. 3A is a perspective view of a frame according to the instant disclosure.

FIG. 3B is a perspective view of a frame according to the instant disclosure.

FIG. 3C is a perspective view of a frame according to the instant disclosure.

FIG. 4 is a partial side view of glass construction according to the instant disclosure.

FIG. 5 is a side view of another glass construction according to the instant disclosure.

FIG. 6 is a side view of another glass construction according to the instant disclosure.

Repeated use of reference characters in the specification and drawings is intended to represent the same or analogous features or elements of the disclosure, even when the numbers increase by 100 from figure-to-figure. It should be understood that numerous other modifications and examples can be devised by those skilled in the art, which fall within the scope and spirit of the principles of the disclosure.

DESCRIPTION

Reference will now be made in detail to certain embodiments of the disclosed subject matter, examples of which are illustrated in part in the accompanying drawings. While the disclosed subject matter will be described in conjunction with the enumerated claims, it will be understood that the exemplified subject matter is not intended to limit the claims to the disclosed subject matter.

This disclosure is generally directed to three-dimensional (3D) cold formed glass displays and methods for making the same. The methods described herein significantly simplify the manufacturing process for glass constructions for automobile interiors, among other applications, because they do not require adhesives that develop tack rapidly and cure quickly. Further, the methods described herein do not require clamping or mechanically restraining a glass construction for a time sufficient for the adhesive interlayer to provide sufficient tack and substantial creep resistance (e.g., partial or complete cure/curing of the adhesive layer/interlayer). The methods described herein not only simply the manufacturing process for glass construction, but also increase reliability of the glass construction because tension and/or shear are not introduced until after the adhesive interlayer is substantially cured.

The disclosure also generally relates to a frame construction comprising:

a glass substrate having first and second major surfaces and at least one curvature;

at least one connector layer including a plurality of mechanical restrains, the connector layer having third and fourth major surfaces;

at least one adhesive layer located between the glass substrate second major surface and the connector layer third major surface; and

a curved surface comprising a plurality of mechanical restrain receptacles engaging the plurality of mechanical restrains;

wherein the curved surface defines the at least one curvature, the at least one curvature having a bend radius of about 60 mm or greater;

wherein the engagement of the plurality of mechanical restrain receptacles and the plurality of mechanical restrains at least initially maintains the at least one curvature (e.g., a convex curve, a concave curve or combinations thereof). After cure, the adhesive layer can substantially maintains the at least one curvature.

The disclosure also relates to a frame construction comprising:

a glass substrate having first and second major surfaces and at least one curvature;

a segmented frame having fifth and sixth major surfaces and including at least one curved segment engaged with at least one substantially flat segment; and

at least one adhesive layer located between at least a portion of the glass substrate second major surface and at least a portion of the segmented frame fifth major surface;

wherein the at least one curved segment defines the at least one curvature, the at least one curvature having a bend radius of about 60 mm or greater;

wherein the engagement of the at least one curved segment with the at least one substantially flat segment maintains the at least one curvature (e.g., a convex curve, a concave curve or combinations thereof). The segmented frame can include at least one curved segment comprising a first end a second end, the first end engaged with a first substantially flat segment and the second end engaged with a second substantially flat segment.

The disclosure also relates to a frame construction comprising:

a glass substrate having first and second major surfaces and at least one curvature;

at least one connector layer including a plurality of mechanical restraint receptacles, the connector layer having third and fourth major surfaces;

at least one adhesive layer located between the glass substrate second major surface and the connector layer third major surface; and

a curved surface comprising a plurality of mechanical restrains engaging the plurality of mechanical restrain receptacles;

wherein the curved surface comprises a radius of curvature of about 60 mm or greater;

wherein the engagement of the plurality of mechanical restrain receptacles and the plurality of mechanical restrains at least initially maintains the at least one curvature.

The methods described herein include first adhering a substantially flat glass component (e.g., a substantially flat sheet glass component) to a substantially flat, connector layer comprising a plurality of mechanical restraints located on a back side of the connector layer, on the side that faces away from and would be substantially invisible to a user. The connector layer can be flexible or un-flexible. For example, the connector layer can have a Young's modulus of from about less than 0.01 GPa to about 400 GPa, such as from less than about 0.01 GPa to about 1 GPa, about 0.1 GPa to about 5 GPa, about 5 GPa to about 100 GPa or about 50 GPa to about 200 GPa.

The glass component is adhered to the connector layer using any suitable adhesive, thereby producing a glass construction comprising a plurality of mechanical restraints. Once the adhesive develops sufficient tack and substantial creep resistance, the plurality of mechanical restrains on the glass construction can then be inserted into a corresponding plurality of mechanical restraint receptables located, e.g., on a curved surface of an automobile interior, thereby bending the glass construction to substantially match the shape of, e.g., a portion of an automobile interior. Alternatively, the plurality of mechanical restrains on the glass construction can be inserted into a corresponding plurality of mechanical restraint receptables located on a flexible frame that can then be fastened, e.g., on a curved surface of an automobile interior.

The methods described herein also include first adhering a substantially flat g lass component (e.g., a substantially flat sheet glass component) to a substantially flat, connector layer comprising a plurality of mechanical restraint receptables on a back side of the connector layer, on the side that faces away from and would be substantially invisible to a user. The glass component is adhered to the connector layer using any suitable adhesive, thereby producing a glass construction comprising a plurality of mechanical restraint receptables. Once the adhesive develops sufficient tack and substantial creep resistance, the plurality of mechanical restraint receptables on the glass construction can be engaged with a corresponding plurality of mechanical restraints located, e.g., on a curved surface of an automobile interior, thereby bending the glass construction to substantially match the shape of, e.g., a portion of an automobile interior.

An example of a glass construction 100 is shown in FIG. 1A, which forms glass construction 200 upon engagement with frame 150. Glass construction 100/200 includes a glass substrate 110, an adhesive interlayer 120, and a connector layer 130. Connector layer 130, in turn, includes a plurality of mechanical restrains 160, 161, 161′, 162, and 162′. The mechanical restraints can insert into a plurality of mechanical restrain receptacles 170, 172, 172′, 173, and 173′, respectively, located in frame 150. In the embodiment shown, frame 150 comprises a curved surface 151.

Although glass construction 100/200 can include a connector layer that extends substantially the entire length of glass substrate 110 and adhesive interlayer 120, segmented connector layers are contemplated herein (see FIG. 1B), wherein, e.g., mechanical restraint 161 and 162 would be located on a first connector layer 130′ and second connector layer 130″, respectively; mechanical restraints 161′ and 162′ would be located on a third connector layer 130A and fourth connector layer 130B; and mechanical restraint 160 would be located on a fifth connector layer 130. Such segmented connector layers can be flexible. Or such segmented connector layers can be non-flexible.

In other examples, connector layer 130, 130′, 130″, or 130′″ can comprise features to make it anisotropically bend to drive dimensional bending and minimize warp in glass substrate 110. Features that can allow the connector layer to anisotropically bend to drive dimensional bending and minimize warm in glass substrate 110 include various patterns (e.g., linear patterns) 101 in the connector layer, wherein the patterns have an axis that is orthogonal to a bend axis 102 in the glass construction 100. See FIG. 1E. An example of such a pattern is shown in FIGS. 1E-1G, wherein FIG. 1E is a perspective view of a glass construction 100 similar to the one shown in FIG. 1A, FIG. 1F is a bottom view of a patterned connector layer 130, and FIG. 1G is a perspective view of the patterned connector layer shown in FIG. 1F.

The pattern shown in FIG. 1E appear exaggerated to illustrate the presence of a pattern. But the pattern can be a microreplicated pattern or a pattern applied to the connector layer by embossing the connector layer using any suitable method known in the art for generating microreplicated and embossed patterns. Or the pattern can be created by using any suitable method known in the art.

In the example provided in FIG. 1A, at least receptacles 172, 172′, 173, and 173′ are defined by edges of frame gaps 180 and 180′ present in frame 150. FIG. 1A not only shows glass construction 100, and its parts, but also how glass construction 100 engages mechanical restrain receptacles 170, 172, 172′, 172′, and 173′ in frame 150 to form frame construction 200. Frame 150 in frame construction 200 is sufficiently rigid to impose its shape on glass construction 100.

Although the shape provided in FIG. 1A is curvilinear, frame 150 (and the other frames described herein) can impart any suitable shape on the glass substrate including an S-shape, C-shape, a J-shape, an S-shape, or a V-shape. In some instances, the frames described herein can be complexly curved and can have a distinct radius of curvature in at least two different regions (e.g., as in a windshield) or in at least two independent directions, which may be the same or different radii from one another.

FIG. 1C shows another example of a glass construction 100, which forms glass construction 200 upon engagement with frame 150. In FIG. 1C however, the frame 150, not the connector layer 130, is what includes a plurality of mechanical restrains 160, 161, 161′, 162, and 162′. The mechanical restraints can insert into a plurality of mechanical restrain receptacles 170, 172, 172′, 173, and 173′, respectively, located in connector layer 130.

FIG. 1D shows another example of a glass construction 200. FIG. 1D can have any of the configurations of connector layer 130 and frame 150 described herein. But the glass construction 200 shown in FIG. 1D effectively shows the construction in FIG. 1A, with a display 190 mounted thereon. The constructions (e.g., 100 and 200) allow for the mounting (e.g. adhesion) of a display or other device onto glass construction 100 from, e.g., FIGS. 1A and 10 , while the glass construction 100 is flat. Once the adhesive layer develops sufficient tack and creep resistance, the construction 100 can be engaged with the frame 150 to form construction 200 with the display thereon. One should recognize that the display could also be mounted, e.g., onto the constructions 200 shown in FIGS. 1A-1C, following engagement of glass construction 100 with frame 150.

In any of the constructions shown herein (e.g., FIGS. 1A-1C), the frame need not be monolithic and can be segmented as shown in FIG. 2 . FIG. 2 is a side view of a segmented frame where the frame is, in this example, segmented into three parts, namely, 150′, 150″, and 150′″. Frame 150′ comprises a plurality of holes 132; frame 150″ comprises a plurality of holes 132′; and frame 150′″ comprises a plurality of holes 133 and 133′. Even though a plurality of holes 132 is shown, frame 150′ could have a single hole. Further, even though a plurality of holes 132′ is shown, frame 150″ could have a single hole. Finally, even though a plurality of holes 133 and 133′ is shown, frame 150′″ could have a single hole 133 or a single hole 133′.

Frame 150′″ is configured such that, when glass substrate 110 is curved, the plurality of holes 133 can line up with the plurality of holes 132 and the plurality of holes 133′ can line up with the plurality of holes 132′. Frame 150′″ can then be fastened to frames 150′ and 150″ by inserting, e.g., pins, rods or bolts into the plurality holes 132 and 132′, such that the pins, rods or bolts would extend through or into the plurality of holes 133 and the plurality of holes 133′, thereby maintaining the shape, in this example a curve shaped, of glass substrate 110 in frame construction 400. Frame construction 400 can optionally have an adhesive 134 such that the entire construction is adhesive backed.

Frames 150, 150′, 150″, and 150′″ can have any suitable thickness. In some examples, the thickness of a frame can vary within the same frame. In other examples, such as the example shown in FIG. 2 , frames 150′ and 150″ can be the same thickness, but frame 150′″ can be a different thickness than either frame 150′ or frame 150″. The frames described herein can have a thickness that can be in a range from about 0.5 mm to about 20 mm; and all ranges and sub-ranges therebetween.

Frames 150, 150′, 150″, and 150′″ can be made of any suitable material, including any material that is sufficiently rigid to impose its shape on glass construction 100. That is not to say, however, that frame 150 or 150′″ cannot deform slightly from its shape once glass construction 110 is mounted or fastened thereon. In some examples, frames 150, 150′, 150″, and 150′″ can be metal, made of aluminum, magnesium alloy, stainless steel or combinations thereof, and forms a curved metal frame. But other materials are contemplated herein for frames 150, 150′, 150″, and 150′″, including carbon fiber and plastics that would be sufficiently rigid to impose its shape on glass construction 100 and 300.

FIG. 3A is a perspective view of frame 150 in FIG. 1A showing mechanical restrain receptacles 170, 172, 172′, 173, and 173′, respectively. It is clear from FIG. 3A that frame 150 can have a plurality of mechanical restrain receptacles 170 located along frame midsection 174 into which a plurality of mechanical restraints 160 can insert and engage the plurality of mechanical restraint receptacles 170. Although mechanical restraint receptacles 170 are located along the same axis, they need not be. FIG. 3A also shows mechanical restraint receptacles 172, 172′ and 173, 173′ formed by edges on frame 200 that can be engaged by mechanical restrains 161, 161′ and 162, 162′. In the example provided in FIG. 3A, at least receptacles 172, 172′, 173, and 173′ are defined by edges of frame gaps 180 and 180′ present in frame 150.

FIG. 3B is a perspective view of frame 150 in FIG. 1A showing mechanical restrain receptacles 170, 172, 172′, 173, and 173′, respectively. It is clear from FIG. 3B that frame 150 can have a plurality of mechanical restrain receptacles 170 located along frame midsection 174 into which a plurality of mechanical restraints 160 can insert and engage the plurality of mechanical restraint receptacles 170. Although mechanical restraint receptacles 170 are located along the same axis, they need not be. FIG. 3B also shows mechanical restraint receptacles 172, 172′ and 173, 173′ that, in this case, would surround engaged mechanical restrains 161, 161′ and 162, 162′.

FIG. 3C is a perspective view of frame 150 showing mechanical restrain receptacles 173 into which a plurality of mechanical restraints 160 can insert and engage the plurality of mechanical restraint receptacles 173. In the example given in FIG. 3C, there is no frame midsection 174 and the receptables 173 are located about the perimeter of frame 150.

FIG. 4 is a partial side view of glass construction 500 in FIG. 1A including a glass substrate 110 and an adhesive interlayer 120, but has a segmented connector layer 130, segmented to such an extent that glass construction 500, which could be used to form a glass construction similar to glass construction 200, comprise substantially only a plurality of mechanical restrains 160, 162, and 162′ directly adhered to glass substrate 110 via adhesive layer 120.

The mechanical restraints described herein can have any suitable shape that would allow them to engage the plurality of mechanical restraint receptacles. In other words, even though arrow-shaped mechanical restraints are shown in FIG. 1A and FIG. 4 , the mechanical restraints can have any suitable shape. And although mechanical restraints 160, 162, and 162′, as well as mechanical restraints 161 and 161′, are shown in a snap-fit configuration, there are no limitations as to how mechanical restrains 160, 161, 161′, 162, and 162′ can engage mechanical restrain receptacles 170, 172, 172′, 173, and 173′. For example, mechanical restrains 160, 161, 161′, 162, and 162′ can engage mechanical restrain receptacles 170, 172, 172′, 173, and 173′ by interference fit, snap fit, and combinations thereof. In some instances, in fact, mechanical restrains 160, 161, 161′, 162, and 162′ could be threaded and could extend through receptacles 170, 172, 172′, 173, and 173′ and could be held to form frame construction using, e.g., a nut. In addition, the mechanical restrains 160, 161, 161′, 162, and 162′ can engage mechanical restrain receptacles 170, 172, 172′, 173, and 173′ using heat-staking, where a plastic restraint material can be melted or welded to frame 150.

FIGS. 5 and 6 are additional glass constructions 100 contemplated herein, wherein connector layer 130 can be segmented.

Glass construction 100 is shown in FIG. 5 , which forms glass construction 200 upon engagement with frame 150 and, in the case of the construction shown in FIG. 5 , also upon engagement with a suitable vacuum chuck and a suitable second adhesive layer (e.g., the adhesives described herein) 121, where the vacuum chuck causes glass construction 100 to deform and contact frame 150. The frame 150, the glass construction 100 or both the frame 150 and the glass construction 100 can comprise a second adhesive layer 121 before glass construction 200 is formed. Glass construction 100/200 includes a glass substrate 110, adhesive layers 120 and 120′ and connector layers 130 and 130′, wherein connector layers 130 and 130′ include mechanical restraint receptacles 131 and 131′, which engage frame 150 as shown.

Other configurations for connector layers 130 and 131′ are contemplated herein. For example, the mechanical restraint receptacles 131 and 131′ can comprise threads to each accept a screw that would insert through a hole in frame 150. In sum, any of the mechanical restraint receptacle/mechanical restraint configurations described herein apply equally to FIG. 5 . Further, second adhesive layer 121 can assist in maintaining the at least one curvature or can entirely maintain the at least one curvature, independent of mechanical restraint receptacles 131/131′ engaged with frame 150, such that the connector layers 130/130′, including mechanical restraint receptacles 131/131′, could be removed, if desired.

Another glass construction 100 is shown in FIG. 6 , which forms glass construction 200 upon engagement with frame 150. Glass construction 100/200 includes a glass substrate 110, adhesive layers 120 and 120′ and connector layers 130 and 130′, wherein connector layers 130 and 130′ include mechanical restraint receptacles 131 and 131′, which engage uncurved surface 152 as shown.

Other configurations for connector layers 130 and 131′ are contemplated herein. For example, the mechanical restraint receptacles 131 and 131′ can comprise threads to each accept a screw that would insert through a hole in uncurved surface 152. In sum, any of the mechanical restraint receptacle/mechanical restraint configurations described herein apply equally to FIG. 6 . Further, as indicated in FIG. 6 , one can laminate a display to construction 200 using any suitable method known in the art. In addition, or alternatively, one can apply a second adhesive layer (not shown) to at least a portion of the concave or convex surface of glass substrate 110, where the second adhesive layer can engage a curved surface 151. The curved surface 151 itself can include a third adhesive layer. Once the second adhesive layer (and third adhesive layer, if present) cures, the second adhesive layer (and third adhesive layer, if present) can entirely maintain the at least one curvature. At that point, uncurved surface 152 can be removed. Further still, glass construction 100/200 can include additional mechanical restraint receptacles (not shown), which engage the curved surface 151 such that the additional mechanical restraint receptacles can assist in maintaining the at least one curvature.

As used herein, the term “glass substrate” is used in its broadest sense to include any object made wholly or partly of glass. Glass substrates include laminates of glass and non-glass materials, laminates of glass and crystalline materials, and glass-ceramics (including an amorphous phase and a crystalline phase). The glass substrates may be transparent or opaque and can optionally include a colorant that provides a specific color. The glass substrates described herein can be cold formed.

As used herein, the terms “cold-formed,” “cold-bent,” or “cold-bending” refers to curving the glass substrates described herein at a cold-forming temperature which is less than the softening point of the glass substrate. The term “cold-bendable” refers to the capability of a glass substrate to be cold-bent to any given radius of curvature.

Suitable glass substrates for use herein include, but are not limited to, soda lime silicate, aluminosilicate, borosilicate, boroaluminosilicate, alkali-containing aluminosilicate, alkali-containing borosilicate, and alkali-containing boroaluminosilicate. Also included are laminates.

The glass substrates can be strengthened using any suitable method known in the art, including by including compressive stress (CS) into the glass substrate, that extends from a surface to a depth of compression (DOC); by utilizing a mismatch of the coefficient of thermal expansion between portions of the glass substrate to create a compressive stress region and a central region exhibiting a tensile stress; thermally by heating the glass substrate to a temperature above the glass transition point and then rapidly quenching; and chemically by ion exchange, where, e.g., ions at or near the surface of the glass substrate are replaced by, or exchanged with, larger ions having the same valence or oxidation state.

The thickness of the glass substrates can be tailored to allow the glass substrate to be more flexible to achieve the desired radius of curvature. The thickness of the glass substrate can be substantially constant along its length. The glass substrate can have any suitable thickness, of about 0.2 mm to about 3 mm (e.g., about 0.2 mm to about 2 mm and about 0.4 mm to about 1.1 mm). Further, the glass substrate, once incorporated into, e.g., glass constructions 200 and 400, can have any suitable bending radius, or radius of curvature. The radius of curvature can be, for example, about 20 mm or greater, 40 mm or greater, 50 mm or greater, 60 mm or greater, 100 mm or greater, 250 mm or greater or 500 mm or greater. For example, the radius of curvature can be in a range from about 60 mm to about 1200 mm. Further still, the glass substrate can have any suitable width, e.g., in a range from about 5 cm to about 250 cm; and any suitable length, e.g., in a range from about 5 cm to about 250 cm.

The adhesive layer 120 can have any suitable bond line, which is defined by at least one of the adhesive's thickness and bezel width. For example, the adhesive can have a thickness of about 5 mm or less, such as from about 200 μm to about 1 mm. The adhesive layer 120 can also have any suitable bezel width. For example, can have a bezel width of about 50 mm or less, such as 25 mm or less, such as in a range from about 1 mm to about 15 mm.

Suitable adhesives include 2-part Toughened Epoxy (for example, Masterbond JP21TDCHT-LO, 3M Scotch Weld Epoxy DP460 Off-white); Flexible Epoxy (for example, Masterbond EP21TDC-2LO, 3M Scotch Weld Epoxy 2216, 3M Scotch Weld Epoxy DP125, DP105, DP100+, Epoxy 2216 available from 3M®, Saint Paul, Minn.); Toughened Acrylics (for example, LORD Adhesive 403, 406 or 410 Acrylic adhesives with LORD Accelerator 19 or 19 GB w/LORD AP 134 primer, LORD Adhesive 850 or 852/LORD Accelerator 25 GB, Loctite HF8000, Loctite AA4800); polyurethanes such as 3M Scotch Weld DP640, DP604NS, DP620NS available from 3M®, Saint Paul, Minn., Loctite HHD 3542, Betamate 73100/002, 73100/005, 73100/010, Betaseal X2500, and Betalink K2, from Dupont®, Wilmington, Del.; silane modified polymers such as TEROSON RB IX, also known as TEROSTAT MS 9399, Teroson MS 930/Teroson MS 9371 and TEROSON MS 647, available from Loctite® and VIASeal X13, silicones or siloxanes, such as Dow Corning 7091, 995 Silicone, Dow Corning HM-2600 Assembly sealant, Dow Corning HM-2500 Assembly sealant, 121 Structural Glazing Sealant as well as other organo-functional siloxanes.

Values expressed in a range format should be interpreted in a flexible manner to include not only the numerical values explicitly recited as the limits of the range, but also to include all the individual numerical values or sub-ranges encompassed within that range as if each numerical value and sub-range were explicitly recited. For example, a range of “about 0.1% to about 5%” or “about 0.1% to 5%” should be interpreted to include not just about 0.1% to about 5%, but also the individual values (e.g., 1%, 2%, 3%, and 4%) and the sub-ranges (e.g., 0.1% to 0.5%, 1.1% to 2.2%, 3.3% to 4.4%) within the indicated range. The statement “about X to Y” has the same meaning as “about X to about Y,” unless indicated otherwise. Likewise, the statement “about X, Y, or about Z” has the same meaning as “about X, about Y, or about Z,” unless indicated otherwise.

In this document, the terms “a,” “an,” or “the” are used to include one or more than one unless the context clearly dictates otherwise. The term “or” is used to refer to a nonexclusive “or” unless otherwise indicated. In addition, it is to be understood that the phraseology or terminology employed herein, and not otherwise defined, is for the purpose of description only and not of limitation. Any use of section headings is intended to aid reading of the document and is not to be interpreted as limiting; information that is relevant to a section heading may occur within or outside of that particular section. Furthermore, all publications, patents, and patent documents referred to in this document are incorporated by reference herein in their entirety, as though individually incorporated by reference. In the event of inconsistent usages between this document and those documents so incorporated by reference, the usage in the incorporated reference should be considered supplementary to that of this document; for irreconcilable inconsistencies, the usage in this document controls.

In the methods described herein, the steps can be carried out in any order without departing from the principles of the invention, except when a temporal or operational sequence is explicitly recited. Furthermore, specified steps can be carried out concurrently unless explicit claim language recites that they be carried out separately. For example, a claimed step of doing X and a claimed step of doing Y can be conducted simultaneously within a single operation, and the resulting process will fall within the literal scope of the claimed process.

The term “about” as used herein can allow for a degree of variability in a value or range, for example, within 10%, within 5%, or within 1% of a stated value or of a stated limit of a range.

The term “substantially” as used herein refers to a majority of, or mostly, as in at least about 50%, 60%, 70%, 80%, 90%, 95%, 96%, 97%, 98%, 99%, 99.5%, 99.9%, 99.99%, or at least about 99.999% or more.

The present disclosure provides for the following embodiments, the numbering of which is not to be construed as designating levels of importance:

Embodiment 1 relates to a frame construction comprising:

a glass substrate having first and second major surfaces and at least one curvature;

at least one connector layer including a plurality of mechanical restrains, the connector layer having third and fourth major surfaces;

at least one adhesive layer located between the glass substrate second major surface and the connector layer third major surface; a frame comprising a plurality of mechanical restrain receptacles engaging the plurality of mechanical restrains;

wherein the frame comprises a curved surface that comprises a radius of curvature of about 60 mm or greater;

wherein the engagement of the plurality of mechanical restrain receptacles and the plurality of mechanical restrains at least initially maintains the at least one curvature of the glass substrate.

Embodiment 2 relates to the construction of Embodiment 1, wherein the connector layer is flexible.

Embodiment 3 relates to the construction of Embodiment 1 or Embodiment 2, further comprising a second adhesive layer located between the glass substrate second major surface and the curved surface of the frame.

Embodiment 4 relates to the construction of any one of Embodiments 1 through 3, wherein the connector layer is segmented.

Embodiment 5 relates to the construction of any one of Embodiments 1 through 4, wherein the connector layer is bonded to the glass substrate in a minimum number of locations on the glass substrate sufficient to at least initially maintain the at least one curvature of the glass substrate.

Embodiment 6 relates to the construction of Embodiment 5, wherein the connector layer is segmented to such an extent that the connector layer comprises substantially only a plurality of mechanical restrains adhered to the glass substrate.

Embodiment 7 relates to the construction of any one of Embodiments 1 through 6, wherein the radius of curvature of the curved surface is from about 60 mm to about 10,000 mm.

Embodiment 8 relates to the construction of any one of Embodiments 1 through 7, wherein the glass substrate comprises a composition selected from the group consisting of soda lime silicate, aluminosilicate, borosilicate, boroaluminosilicate, alkali-containing aluminosilicate, alkali-containing borosilicate, and alkali-containing boroaluminosilicate.

Embodiment 9 relates to the construction of any one of Embodiments 1 through 8, wherein the glass substrate has a thickness measured from the first major surface to the second major surface of about 0.2 mm to about 2 mm.

Embodiment 10 relates to the construction of any one of Embodiments 1 through 9, wherein the curved surface is a metal curved surface.

Embodiment 11 relates to the construction of Embodiment 10, wherein the curved metal frame is formed of aluminum, magnesium alloy, stainless steel or combinations thereof.

Embodiment 12 relates to the construction of any one of Embodiments 1 through 11, wherein the at least one adhesive layer comprises an epoxy, a polyurethane, an acrylate, a silane modified polymer or a silicone.

Embodiment 13 relates to the construction of Embodiment 1, wherein the adhesive layer has a thickness in a range from about 200 μm to about 5 mm.

Embodiment 14 relates to a frame construction comprising:

a glass substrate having first and second major surfaces and at least one curvature;

a segmented frame having first and second opposing major surfaces and including at least one curved segment engaged and at least one substantially flat segment; and

at least one adhesive layer located between at least a portion of the glass substrate second major surface and at least a portion of the segmented frame first major surface;

wherein the at least one curved segment comprises a curved surface, having a bend radius of about 60 mm or greater;

wherein the engagement of the at least one curved segment with the at least one substantially flat segment maintains the at least one curvature of the glass substrate.

Embodiment 15 relates to the construction of Embodiment 14, wherein the at least one curved segment comprises a first end a second end, wherein the first end engages with a first substantially flat segment and the second end engaged with a second substantially flat segment.

Embodiment 16 relates to the construction of Embodiment 14 or Embodiment 15, further comprising a second adhesive layer located between the glass substrate second major surface and the curved surface of the frame.

Embodiment 17 relates to the construction of any one of Embodiments 14 through 16, wherein the radius of curvature of the curved surface is from about 60 mm to about 10,000 mm.

Embodiment 18 relates to the construction of any one of Embodiments 14 through 17, wherein the glass substrate comprises a composition selected from the group consisting of soda lime silicate, aluminosilicate, borosilicate, boroaluminosilicate, alkali-containing aluminosilicate, alkali-containing borosilicate, and alkali-containing boroaluminosilicate.

Embodiment 19 relates to the construction of any one of Embodiments 14 through 18, wherein the glass substrate has a thickness measured from the first major surface to the second major surface of about 0.2 mm to about 2 mm.

Embodiment 20 relates to the construction of any one of Embodiments 14 through 19, wherein the curved surface is a metal curved surface.

Embodiment 21 relates to the construction of Embodiment 20, wherein the curved metal frame is formed of aluminum, magnesium alloy, stainless steel or combinations thereof.

Embodiment 22 relates to the construction of any one of Embodiments 14 through 21, wherein the at least one adhesive layer comprises an epoxy, a polyurethane, an acrylate, a silane modified polymer or a silicone.

Embodiment 23 relates to the construction of any one of Embodiments 14 through 22, wherein the adhesive layer has a thickness in a range from about 200 μm to about 5 mm. 

What is claimed is:
 1. A frame construction comprising: a glass substrate having first and second major surfaces and at least one curvature; at least one connector layer including a plurality of mechanical restraints, the connector layer having third and fourth major surfaces; at least one adhesive layer located between the glass substrate second major surface and the connector layer third major surface; a frame comprising a plurality of mechanical restraint receptacles engaging the plurality of mechanical restraints; wherein the frame comprises a curved surface that comprises a radius of curvature of about 60 mm or greater; wherein the engagement of the plurality of mechanical restraint receptacles and the plurality of mechanical restraints at least initially maintains the at least one curvature of the glass substrate.
 2. The frame construction of claim 1, wherein the connector layer is flexible.
 3. The frame construction of claim 1, further comprising a second adhesive layer located between the glass substrate second major surface and the curved surface of the frame.
 4. The frame construction of claim 1, wherein the connector layer is segmented.
 5. The frame construction of claim 1, wherein the connector layer is bonded to the glass substrate in a minimum number of locations on the glass substrate sufficient to at least initially maintain the at least one curvature of the glass substrate.
 6. The frame construction of claim 5, wherein the connector layer is segmented to such an extent that the connector layer comprises substantially only a plurality of mechanical restraints adhered to the glass substrate.
 7. The frame construction of claim 1, wherein the radius of curvature of the curved surface is from about 60 mm to about 10,000 mm.
 8. The frame construction of claim 1, wherein the glass substrate comprises a composition selected from the group consisting of soda lime silicate, aluminosilicate, borosilicate, boroaluminosilicate, alkali-containing aluminosilicate, alkali-containing borosilicate, and alkali-containing boroaluminosilicate.
 9. The frame construction of claim 1, wherein the glass substrate has a thickness measured from the first major surface to the second major surface of about 0.2 mm to about 2 mm.
 10. The frame construction of claim 1, wherein the curved surface is a metal curved surface.
 11. The frame construction of claim 10, wherein the curved metal frame is formed of aluminum, magnesium alloy, stainless steel or combinations thereof.
 12. The frame construction of claim 1, wherein the at least one adhesive layer comprises an epoxy, a polyurethane, an acrylate, a silane modified polymer or a silicone.
 13. The frame construction of claim 1, wherein the adhesive layer has a thickness in a range from about 200 μm to about 5 mm.
 14. A frame construction comprising: a glass substrate having first and second major surfaces and at least one curvature; a segmented frame having first and second opposing major surfaces and including at least one curved segment engaged and at least one substantially flat segment; and at least one adhesive layer located between at least a portion of the glass substrate second major surface and at least a portion of the segmented frame first major surface; wherein the at least one curved segment comprises a curved surface, having a bend radius of about 60 mm or greater; wherein the engagement of the at least one curved segment with the at least one substantially flat segment maintains the at least one curvature of the glass substrate.
 15. The construction of claim 14, wherein the at least one curved segment comprises a first end a second end, wherein the first end engages with a first substantially flat segment and the second end engaged with a second substantially flat segment.
 16. The construction of claim 14, further comprising a second adhesive layer located between the glass substrate second major surface and the curved surface of the frame.
 17. The construction of claim 14, wherein the radius of curvature of the curved surface is from about 60 mm to about 10,000 mm.
 18. The construction of claim 14, wherein the glass substrate comprises a composition selected from the group consisting of soda lime silicate, aluminosilicate, borosilicate, boroaluminosilicate, alkali-containing aluminosilicate, alkali-containing borosilicate, and alkali-containing boroaluminosilicate.
 19. The construction of claim 14, wherein the glass substrate has a thickness measured from the first major surface to the second major surface of about 0.2 mm to about 2 mm.
 20. The construction of claim 14, wherein the curved surface is a metal curved surface. 